Analytical method of the polychlorinated biphenyls in soil using GC/ECD and GC/MS

GC/ECD 및 GC/MS을 이용한 토양 중 PCBs 분석방법 고찰

  • Kim, Tae-Seung (National institute of Environmental Research, Environmental Diagnostics Research Department) ;
  • Shin, Sun-Kyoung (National institute of Environmental Research, Environmental Measurement Standards Department) ;
  • Yoon, Jeong-Ki (National institute of Environmental Research, Environmental Diagnostics Research Department) ;
  • Kim, Jong-Ha (National institute of Environmental Research, Environmental Diagnostics Research Department) ;
  • Kim, Hyoung Seop (Korea Environment & Resources Corporation) ;
  • Lee, Jeong Ah (National institute of Environmental Research, Environmental Diagnostics Research Department)
  • 김태승 (국립환경과학원 환경진단연구부) ;
  • 신선경 (국립환경과학원 환경측정기준부) ;
  • 윤정기 (국립환경과학원 환경진단연구부) ;
  • 김종하 (국립환경과학원 환경진단연구부) ;
  • 김형섭 (한국환경자원공사 기술센터) ;
  • 이정아 (국립환경과학원 환경진단연구부)
  • Received : 2007.02.01
  • Accepted : 2007.02.26
  • Published : 2007.04.28

Abstract

This study was investigated both the Korean official soil test method and the international various methods for PCBs in soil sample. The analytical guideline of PCBs in contaminated soil were proposed based on the official soil test methods by discussing the extraction, column cleanup, instrumental conditions, quantification methods of peak matching and individual isomers. The total 28 soil samples were selected by consideration of PCBs-contamination, land use etc., and then analyzed using gas chromatography/electron capture detection (GC/ECD) and gas chromatography/mass spectrometry(GC/MS). In this study, the PCBs were not detected as peak matching method using GC/ECD, but PCBs detected $0.002{\sim}0.487{\mu}g/kg$ using GC/MS in background concentrations.

Keywords

PCBs;Soil;GC/ECD;Aroclor;GC/MS

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