Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Preparation and Adhesive Properties of Acrylate Copolymer with Siloxane Group

실록산기를 함유한 아크릴 공중합체의 제조 및 점착특성

  • Yoon, Keun-Byoung (Department of Polymer Science, Engineering College, Kyungpook National University) ;
  • Noh, Young-Joo (LCD Business, Samsung Electronics Co. Ltd.) ;
  • Lee, Dong-Ho (Department of Polymer Science, Engineering College, Kyungpook National University)
  • 윤근병 (경북대학교 고분자공학과) ;
  • 노영주 ((주)삼성전자 LCD 총괄) ;
  • 이동호 (경북대학교 고분자공학과)
  • Received : 2007.01.25
  • Accepted : 2007.02.14
  • Published : 2007.04.10

Abstract

Siloxane monomer and oligomer were introduced to n-butyl acrylate and methyl methacrylate copolymer for improvement of water resistance and tactile sensation of acryl-type emulsion. Terpolymerimerization of n-butylacrylate, methyl methacrylate and siloxane monomer or oligomer was carried out in aqueous solution. The glass transition temperature (Tg) of terpolymer decreased with increasing siloxane monomer, however, the Tg of terpolymer increased with increasing siloxane oligomer due to the crosslinking of acrylated end group. The adhesion property and surface energy of the obtained terpolymer decreased with introducing siloxane monomer or oligomer in terpolymer. Decrement of tack and surface energy means the enhancement of water resistance and tactile sensation of the emulsion.

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References

  1. C. Plessis, G. Arzamendi, J. M. Alberdi, M. Agnely, J. R. Leiza, and J. M. Asua, Macromolecules, 34, 6138 (2001) https://doi.org/10.1021/ma0018190
  2. R. Jovanović, K. Ouzineb, T. F. McKenna, and M. A. Dubé, Macromol. Symp., 206, 43 (2004)
  3. J. S. Yoon and H. J. Jin, Polym. Sci. Tech., 7, 412 (1996)
  4. M. Schneider, C. Graillat, A. Guyot, I. Betrémieux, and T. F. McKenna, J. Appl. Polym. Sci., 84, 1935 (2002) https://doi.org/10.1002/app.10514
  5. KR patent 455,761 (2004)
  6. P. Bajaj, M. Goyal, and R. B. Chavan, J. Appl. Polym. Sci., 53, 1771 (1994)
  7. J. Crivello and D. Bi, J. Polym. Sci. Polym. Chem. Ed., 32, 683 (1994)
  8. C. Y. Kan, D. S. Liu, X. Z. Kong, and X. L. Zhu, J. Appl. Polym. Sci., 82, 3194 (2001) https://doi.org/10.1002/app.2178
  9. P. L. Kuo, K. C. Chen, and T. L. Wang, Polymer, 38, 5203 (1997)
  10. C. Iojoiu, J. M. Abadie, V. Harabagiu, M. Pinteala, and B. C. Simionescu, Eur. Polym. J., 36, 2115 (2000) https://doi.org/10.1016/S0014-3057(99)00287-6
  11. F. Cazaux and X. Coquetet, Eur. Polym. J., 31, 521 (1995)
  12. S. H. Yoo, J. H. Lee, J. C. Lee, and J. Y. Jho, Macromolecules, 35, 1146 (2002) https://doi.org/10.1021/ma011467c
  13. J. S. Clarson and J. A. Semlyen, Siloxane Polymers, 332 Prentice Hall Inc., New Jersey (1993)
  14. Y. S. Kim, M. A. Bae, and K. S. Yoon, J. Kor. Chem. Soc., 45, 230 (2001)
  15. J. F. Kenney, T. H. Haddock, R. L. Sun, and H. C. Parreira, J. Appl. Polym. Sci., 45, 355 (1992) https://doi.org/10.1002/app.1992.070450218
  16. H. Lakrout, C. Creton, D. Ahn, and K. R. Shull, Macromolecules, 34, 7448 (2001) https://doi.org/10.1021/ma0020279
  17. J. Comyn, Inter. J. Adhesion & Adhesives, 12, 145 (1992) https://doi.org/10.1016/0143-7496(92)90045-W
  18. A. W. Neuman, Adv. Colloid. Interface Sci., 4, 105 (1974) https://doi.org/10.1016/0001-8686(74)85001-3
  19. A. M. El-Naggar, M. H. Zohdy, S. S. Mohammed, and E. A. Alam, Nucl. Instr. Meth, Phys. Res., B 201, 595 (2003)
  20. A. Galliano, S. Bistac, and J. Schultz, J. Colloid and Interface Sci., 265, 372 (2003) https://doi.org/10.1016/S0021-9797(03)00458-2