Synthesis of 6-(10-Alkylphenothiazine-3-vinylene)-2-methyl-4-dicyanomethylene-4H-pyran

적색발광재료용 6-(10-알킬페노티아진-3-비닐렌)-2-메틸-4-디시아노메틸렌-4H-피란의 합성

  • Chung, Pyung Jin (Department of Materials Science and Engineering, Dankook University) ;
  • Sung, Jin Hee (Department of Materials Science and Engineering, Dankook University)
  • 정평진 (단국대학교 신소재공학과) ;
  • 성진희 (단국대학교 신소재공학과)
  • Received : 2007.07.12
  • Accepted : 2007.12.03
  • Published : 2007.12.10


6-(10-Alkylphenothiazine-3-vinylene)-2-methyl-4-dicyanomethylene-4H-pyran derivatives were synthesized by Knoevenagel condensation. They are red-emitting materials for organic light emitting device (OLED) which composed of electron donor of 6-(10-Alkylphenothiazine-3-vinylene) groups and electron acceptor of -2-methyl-4-dicyanomethylene-4H-pyran groups by a conjugated structure. The structural properties of reaction products were analyzed FT-IR and $^1H-NMR$ spectroscopy. The thermal stabilities and reactivities were measured by melting points and yields. The UV-visibles and PL properties can be determined by exitation spectra and emission spectra, respectively.


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