Sorption and Leaching Studies of Fenitrothion and Tebuconazole in Granular Activated Carbon and Charcoal

Fenitrothion과 Tebuconazole의 입상 활성탄 및 차콜에 의한 흡착과 용탈에 관한 연구

  • Lee, Dong-Ik (Department of Biological Resources and Technology, Yonsei University) ;
  • Chun, So-Ul (Institute of Basic Science, Yonsei University) ;
  • Joo, Young-Kyoo (Department of Biological Resources and Technology, Yonsei University)
  • 이동익 (연세대학교 응용과학부 생물자원공학과) ;
  • 천소을 (연세대학교 기초과학연구소) ;
  • 주영규 (연세대학교 응용과학부 생물자원공학과)
  • Published : 2006.06.01

Abstract

Golf course community has always been concerned about water quality regarding to pesticide and fertilizer managements. This study conducted to investigate sorption and leaching behavior of common pesticides used for golf course in granular activated carbon I (GAC 1), granular activated carbon II(GAC II), and charcoal. We used batch study to investigate the influence of concentrations of Smithion and Folicur and particle sizes of GAC I, GAC II, and charcoal on sorption. Also, column study was used to investigate the leaching effect of Smithion in GAC I and charcoal. We found that sorption of Smithion and Folicur were higher in less $45{\mu}m$ of particle size for GAC I, GAC II, and charcoal compared to $1.7{\sim}2.0mm$ size, and the sorption of Smithion and Folicur in less $45{\mu}m$ of particle size ranged from 90 to 99%. In the column study, there was no difference in leaching effect between GAC I and charcoal. Overall, we found that charcoal might offer a cost effective adsorbent as a pesticides in leachate.

References

  1. 권준호, 이민정, 배상규, 이송우, 나영수, 안창덕, 윤영삼, 송승구. 2004. 활성탄의 종류와 입자 크기에 따른 Toluene의 파과 곡선비교. 대한환경공학회. 추계학술연구발표회 : 1274-1278
  2. 농약공업협회. 2005. 농약사용지침서. 농약공업협회
  3. 류순호. 2000. 토양사전. 서울대학교 출판부
  4. 오상실, 고용구, 현해남, 정종배. 2001. 골프장 모형그린에서 활성탄, Orpar 또는 Zeolite의 처리가 Fenitrothion, Triadimefon, Diniconazole의 용탈에 미치는 영향. Journal of the Korean Society of Agricultural Chemistry & Biotechnology. 44(2) : 97-102
  5. 하상도, 심상국, 이춘옥, 이재옥. 2003. 숯과 활성탄의 기능성과 연구 동향 분석. 식품과학과 산업. 36(2) : 99-105
  6. 한국산업규격. 2003. KS M 1802 활성탄 시험방법. 기술표준원 고시 제03-1533호
  7. 환경부. 2002. 골프장 농약 잔류량 시험방법. 행정간행물등록번호:11-1480000-000635-01
  8. 환경부. 2005a. 2005년 상반기 골프장 농약사용 실태조사 결과. 환경부 보도자료. 2005. 9
  9. 환경부. 2005b. 골프장 농약사용 실태조사 결과. 환경부 보도자료. 2005. 4
  10. 현해남, 오상실, 유순호. 1995. 제주도 대표 토양에서 Alachlor와 Chlorothalonil의 흡착과 이동 연구. 한국환경농학회지. 14(2) : 135-143
  11. 眞田雄三, 鈴本其之, 藤元薰(朴永泰 譯). 2001. 新版 活性炭 基礎와 活用. 東和技術
  12. 中野重和, 田村知子, 北川陸夫. 1990. 最新における活性炭による水處俚伎術. 水處俚伎術. 33(5) : 249-260
  13. Carter, D.L., M.M. Mortland, and  W.D. Kemper. 1986. Specific surface. In : Klute A., ed. Methods of soil analysis. Part 1. 2nd ed. Agron. Monogr. 9. Madison, WI : American Society of Agronomy and Soil Science Society of America. 413-423
  14. Dabrowski, A., P. Podkoscielny,  Z. Hubicki, and M. Barczak. 2005. Adsorption of phenolic compounds by activated carbon - a critical review. Chemosphere. 58 : 1049-1070 https://doi.org/10.1016/j.chemosphere.2004.09.067
  15. Heyse, E., D. Augustijin, P.S.C. Rao, and J.J. Delfino. 2002. Nonaqueous phase liquid dissolution and soil organic matter sorption in porous media: review of system similarities. Critical Reviews in Environmental Science and Technology. 32(4) : 337–397
  16. Government of Cheju province. 1997. In overall survey of middle altitude area of Cheju island
  17. Kyotani, T. 2000. Control of pore structure in carbon. Carbon. 38 : 269-286 https://doi.org/10.1016/S0008-6223(99)00142-6
  18. Letey, J., C.F. Williams, W.J. Farmer, S.D. Nelson, M. Agassi, and M. Ben-Hur. 2000. The role of dissolved organic matter in pesticide transport through soil. In: Ross, L.J. ed. Agrochemical movement : Perspective and scale, pp. 347-360, American Chemical Society, Columbus, OH
  19. Linquist, B.A., P.W. Singleton, R.S. Yost, and K.G. Cassman. 1997. Aggregate size effects on the sorption and release of phosphorus in an Ultisol. Soil Science Society of America Journal. 61(1) : 160-167 https://doi.org/10.2136/sssaj1997.03615995006100010024x
  20. Pelekani, C. and V.L. Snoeyink. 2001. A kinetic and equilibrium study of competitive adsorption between atrazine and Congo red dye on activated carbon : the importance of pore size distribution. Carbon. 39 : 25-37 https://doi.org/10.1016/S0008-6223(00)00078-6
  21. USGA Green Section Staff. 2004. Specifications for a method of putting green construction. USGA, Far Hills, NJ
  22. Xu, F.,  X. Liang,  B. Lin, F. Su, K.W. Schramm, and A. Kettrup. 2002. Linear solvation energy relationships regarding sorption and retention properties of hydrophobic organic compounds in soil leaching column chromatography. Chemosphere. 48 : 553–562