Application of Chiral Ligands Heterogenized over Solid Supports on Enantioselective Catalysis

고체 담체에 고정화된 키랄리간드의 비대칭 촉매반응에의 응용

  • Lee, Kwang-Yeon (Department of Chemical Engineering, Inha university) ;
  • Kawthekar, Rahul B. (Department of Chemical Engineering, Inha university) ;
  • Kim, Geon-Joong (Department of Chemical Engineering, Inha university)
  • 이광연 (인하대학교 생명화학공학부) ;
  • 카테카 라울 (인하대학교 생명화학공학부) ;
  • 김건중 (인하대학교 생명화학공학부)
  • Received : 2006.11.24
  • Published : 2006.12.10

Abstract

The trend towards the application of single enantiomers of chiral compounds is undoubtedly increasing. Among the various methods to obtain one single enantio-riched compound selectively, enantioselective catalysis is the most attractive method. Especially, it is important to increase the activity, selectivity and lifetime of usually expensive chiral catalysts with a minute quantity in the enantioselective synthesis. Immobilization of active homogeneous catalysts is a fashionable topic in asymmetric catalysis, providing the inherent advantage of easy separation and better handling properties. Many different ways have been investigated to improve the enantioselectivity of products and to recycle the catalysts. This review mainly focused on the present scope and limitations of different types of enantioselective heterogeneous catalysts.

Keywords

Immobilization;enantioselectivity;catalysis;chiral compound

Acknowledgement

Supported by : Inha University

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