Applied Chemistry for Engineering (공업화학)
- Volume 16 Issue 3
- /
- Pages.342-347
- /
- 2005
- /
- 1225-0112(pISSN)
- /
- 2288-4505(eISSN)
Synthesis and Properties of Photocurable Dimethylol Propionic Acid modified Hyperbranched Acrylates
광경화형 Dimethylol Propionic Acid 변성 하이퍼브랜치 아크릴레이트의 합성과 물성
- Kim, Dong Kook (Department of Chemistry & Material Science, Hanyang University) ;
- Lim, Jin Kyu (Department of Chemistry & Material Science, Hanyang University) ;
- Kim, Woo Geun (Department of Chemistry & Material Science, Hanyang University)
- Received : 2004.10.18
- Accepted : 2005.03.11
- Published : 2005.06.10
Abstract
Photocurable hyperbranched acrylates were prepared from acrylic acid and hyperbranched polyol (HBP-16, 32, 64). Physical properties of three kinds of photocurable hyperbranched acrylated were investigated. Thermal stability of UV cured film measured by TGA shifted to higher temperature with increasing of functionality. Hardness, abrasion resistance, and tensile strength of UV cured film also increased with increasing functionality of acrylate. Weathering test for UV cured film showed the value of yellow index increased with increasing functionality of acrylate.
File
References
- Y. Kim, J. Polym. Sci., Part A: Polym. Chem., 36, 1685 (1998)
- B. Voit, J. Polym. Sci., Part A: Polym. Chem., 38, 2505 (2000)
- M. Johansson and A. Hult, J. Coat. Tech., 67, 35 (1995)
- H. Huang, J. Zhang, and W. Shi, J. Photopolym. Sci. Tech., 10, 341 (1997) https://doi.org/10.2494/photopolymer.10.341
- H. Wei, H. Kou, W. Shi, H. Yuan, and Y. Chen, Polymer, 42, 6741 (2001) https://doi.org/10.1016/S0032-3861(01)00139-2
- M. Johansson, T. Glauser, G. Rospo, and A. Hult, J. Appl. Polym. Sci., 75, 612 (2000) https://doi.org/10.1002/(SICI)1097-4628(20000131)75:5<612::AID-APP3>3.0.CO;2-1
- H. Wei, Y. Lu, W. Shi, H. Yuan, and Y. Chen, J. Appl. Polym. Sci., 80, 51 (2001) https://doi.org/10.1002/1097-4628(20010404)80:1<51::AID-APP1074>3.0.CO;2-W
- R. Kaneko, M. Jikei, and M. Kakimoto, High Performance Polymers, 14, 53 (2002) https://doi.org/10.1177/0954008302014001451
- H. Kou, A. Asif and W. Shi, European Polymer J., 38, 1931 (2002) https://doi.org/10.1016/S0014-3057(02)00105-2
- S. W. Zhu and W. Shi, Polym. Int., 51, 223 (2002) https://doi.org/10.1002/pi.827
- W. Huanyu, K. Huiguang, and W. Shi, J. Coat. Tech., 75, 939 (2003)
- M. Braithwaite, S. Davidson, R. Holman, C. Lowe, P. K. T. Oldring, M. S. Salim, and C. Wall, Chemistry & technology of UV & EB formulation for coatings, inks & paints, ed. P. K. T. Oldring, SITA Technology, London (1991)
- S. P. Pappas, Radiation curing, Plenum Press, New York (1992)
- S. P. Pappas, UV curing: Science and technology, Technology Marketing Corporation, Connecticut (1983)
- J. C. Jung, Polymer(Korea), 10, 570 (1986)
- C. E. Hoyle and J. F. Kinstle, Radiation curing of polymeric materials, American Chemical Society, Washigton DC (1990)
- G. Orcel, S. Vanpoulle, J. Y. Barraud, J. Y. Boniort, and B. Overton, Wire, 46, 206 (1996)
- A. H. Rodas, R. E. S. Bretas, and A. Reggianni, J. Mater. Sci., 21, 3025 (1986) https://doi.org/10.1007/BF00553332
- M. J. Moon, J. H. Park, and G. D. Lee, J. Korean Ind. Eng., Chem., 2, 175 (1991)
- J. K. Lim, D. K. Kim, and J. Y. Hwang, J. Korean Ind. Eng. Chem., 14, 818 (2003)
- J. K. Lim, D. K. Kim, and W. G. Kim, J. Korean Ind. Eng. Chem., 15, 225 (2004)
- Y. C. Kim and B. J. Lee, J. Korean Ind. Eng. Chem., 13, 538 (2002)
- J. W. Hong, M. Y. Park, H. K. Kim, Y. B. Kim, and H. K. Choi, J. Korean Ind. Eng. Chem., 11, 693 (2000)
- J. W. Hong and H. W. Lee, J. Korean Ind. Eng. Chem., 5, 857 (1994)
- J. K. Lim, D. K. Kim, and W. G. Kim, J. Korean Ind. Eng. Chem., 15, 360 (2004)