• Hwang, Sang-Chul (Dept of Geography & Environmental Engineering, Johns Hopkins University) ;
  • Min, Kyung-Sok (Dept of Environmental Engineering, Kyungpook National University) ;
  • Jeffrey L.Davis (EL, US Army Engineer Research and Development Center)
  • Published : 2004.02.29



Alkaline hydrolysis;Continuous flow stirred-tank reactor;Formate;Oxalate;RDX;TNT


  1. Rosenblatt, D. H., Burrows, E. P., Mitchell, W. R., and Parmer, D. L., 'Organic Explosives and Related Compounds,' The Handbook of Environmental Chemistry, Volume 3, Part G, Hutzinger, O. (Ed.), Springer-Verlag, (1991)
  2. Spain, J. C., 'Biodegradation of nitroaromatic compounds,' Annu. Rev. Microbiol., 49, 523-555 (1995)
  3. Walsh, M. E., Jenkins, T. F., Schnitker, P. S., Elwell, J. W. and Stutz, M. H., US Army Cold Regions Research and Engineering Laboratory, CRREL Special Report 93-5. Hanover, NH (1993)
  4. Peres, C. M. and Agathos, S. N., 'Biodegradation of nitroaromatic pollutants: from pathways to remediation,' Biotechnology Annual Review, 6, 197-220 (2000)
  5. Won, W. D., DiSalvo L. H., and Ng, J., 'Toxicity and mutagenicity of 2,4,6-trinitrotoluene and its metabolites,' Appl. Environ. Microbiol., 31, 576-580 (1976)
  6. US EPA, 2002 Edition of the Drinking Water Standards and Health Advisories. Office of Water, EPA 822-R-02-038. Washington, DC (2002)
  7. Jones, W. H., 'Mechanism of the homogenous alkaline decomposition of cyclomethylenetrinitramine: Kinetics of consecutive second- and first-order reactions. A polarographic analysis for cyclomethylenetrinitroamine' J. Am. Chem. Soc. 76, 829-835 (1954)
  8. Croce, M. and Okamoto, Y., 'Cationic micellar catalysis of the aqueous alkaline hydrolyses of 1,3,5-triaza-l,3,5-trinitrocyclohexane and 1,3,5,7-tetraaza-1,3,5,7-tetranitrocyclooctane,' J. Org. Chem., 44(13), 2100-2103 (1979)
  9. Emmrich, M., 'Kinetics of the alkaline hydrolysis of 2,4,6-trinitrotoluene in aqueous solution and highly contaminated soils,' Environ. Sci. Technol., 33(21), 3802-3805 (1999)
  10. Heilmann, H. M., Wiesmann, U. and Stenstrom, M. K., 'Kinetics of the alkaline hydrolysis of high explosives RDX and HMX in aqueous solution and adsorbed to activated carbon,' Environ. Sci. Technol., 30(5), 1485-1492 (1996)
  11. Hoffsommer, J. C., Kubose, D. A., and Glover, D. J., 'Kinetic isotope effects and intermediate formation for the aqueous alkaline homogenous hydrolysis of 1,3,5-triaza-l,3,5-tribitrocyclohexane (RDX),' J. Phys. Chem., 81(5), 380-385 (1977)
  12. Karasch, C., Popovic, M., Qasim, M. and Bajpai, R. K., 'Alkali hydrolysis of trinitrotoluene,' Appl. Biochem. Biotechnol., 98-100, 1173-1185 (2002)
  13. Vesilind, P. A., Introduction to environmental engineering, PWS Publishing Company, Boston, MA (1997)
  14. HACH, DR/2000 Spectrophotometer Procedures Manual, Hach Company, Loveland, CO (1991)
  15. Pennington, J. C., Thorn, K. A., Inouye, L. S., McFarland, V. A., Jarvis, A. S., Lutz, C. H., Hayes, C. A. and Porter, B. E., Explosives conjugation products in remediation matrices: Final report. Strategic Environmental Research and Development Program Technical Report SERDP-99-4 (1999)
  16. Bruce, P. Y, Organic Chemistry, PrenticeHall, Inc., NJ (1995)
  17. Rieger, P. G. and Knackmuss, H. J., 'Basic Knowledge and Perspectives on Biodegradation of 2,4,6-Trinitrotoluene and Related Nitroaromatic Compounds in Contaminated Soil,' Biodegradation of Nitroaromatic Compounds, Spain J. C. (Ed.), Plenum Press, New York, (1995)
  18. Balakrishnan, V. K., Halasz, A., and Hawari, J., 'Alkaline hydrolysis of the cyclic nitramine explosives RDX, HMX, and CL-20: New insights into degradation pathways obtained by the observation of novel intermediates,' Environ. Sci. Technol., 37, 1838-1843

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