DOI QR코드

DOI QR Code

Luminescence Properties of Ag Doped ZnO as Quantum Dot Materials for Improving Efficiency of Dye-sensitized Solar Cell

염료감응형 태양전지에서 효율 향상을 위한 Quantum Dot 재료로서 Ag가 도핑된 ZnO의 발광 특성 연구

  • 김현주 (한국전기연구원 전자기소자연구그룹) ;
  • 이동윤 (한국전기연구원 전자기소자연구그룹) ;
  • 송재성 (한국전기연구원 전자기소자연구그룹)
  • Published : 2004.09.01

Abstract

Luminescence characteristics of Ag-doped ZnO as the quantum dot materials to increasing the efficiency on dye-sensitized solar cells (DSC) have been studied. Ag doped ZnO powder was produced by the self-sustaining combustion process using ultrasonic spraying heating method. Luminescence wavelength region of the ZnO by Ag doping was shifted to longer wavelength. Tn the case of the Ag doped ZnO powder, broad luminescence spectrum centered on 600nm was observed. On the other hand, we compared PL data of RTA treated ZnO:Ag film at various temperatures because the front electrode of solar cell was in need of the sintering process. In XRD and PL data for RTA treated film at the 500$^{\circ}C$ showed good property. And, it was found that the grain size wasn't growing but only optical property was changed. According to the result of XRD, PL, absorption, emission spectrum and DV-X${\alpha}$ used in theoretical calculation, it is considered to be possible to use Ag doped ZnO as quantum dot material for improving DSC efficiency.

References

  1. J. Phys. Chem. v.99 Potential Dependent Electron Injection in Nanoporous Colloidal ZnO Films P. Hoyer;H. Weller https://doi.org/10.1021/j100038a048
  2. J. Phys. Soc. Jpn. v.45 Application to Metal Clusters H. Adachi;M. Tsukada;C. Satoko https://doi.org/10.1143/JPSJ.45.875
  3. Surface. Science v.58 Molecular cluster theory for dechemisorption of first raw atoms on nikel (100) surfaces D. E. Ellis;H. Adachi;F. W. Averill
  4. Solid State Ionics v.63 Microstructural characterization of nanocrystals of ZnO and CuO obtained from basic salts O. Garcia Martinez;R. M. Rojas;E. Vila J. L.;Martin de Vidales https://doi.org/10.1016/0167-2738(93)90142-P
  5. Solid State Communications v.10-6 no.10 Source of the Yellow luminescence band in GaN by gas-source molecular beam epitaxy and the green luminescence band in single crystal ZnO D. C. Reynolds;D. C. Look;B. Jogai;J. E. Van Nostrand;R. Jones;J. Jenny
  6. Acc. Chem. Res. v.33 Molecular Photovoltaics A. Hagfeldt;M. Gratzel https://doi.org/10.1021/ar980112j
  7. 한국산학연논문집 v.2 no.3 Preparation of ZnO Nano Powder Combustioined using Ultrasonic Spraying Heating Method 김강수;황두선;이강;구숙경;이남희;전치중;김선재