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Integrated Microdisk Gold Electrode Modified with Metal-porphyrin and Metal-phthalocyanines for Nitric Oxide Determination in Biological Media

  • Kim, Il-Kwang (Institute of Basic Natural Science, Chemistry Department, Wonkwang University) ;
  • Bae, Hyun-Ok (Department of Microbiology, College of Medical Science, Wonkwang University) ;
  • Oh, Gi-Soo (Department of Microbiology, College of Medical Science, Wonkwang University) ;
  • Chung, Hun-Taeg (Department of Microbiology, College of Medical Science, Wonkwang University) ;
  • Kim, Young-Jin (Institute of Basic Natural Science, Chemistry Department, Wonkwang University) ;
  • Chun, Hyun-Ja (Institute of Basic Natural Science, Chemistry Department, Wonkwang University)
  • Published : 2003.11.20

Abstract

An integrated gold microdisk electrode was constructed and modified with metal-porphyrin or metal-phthalocyanines for NO determination in biological media. Microanalysis of NO using square wave anodic stripping voltammetry in $1\;{\times}\;10^{-2}$ M $HClO_4$ was optimal when the accumulation potential was 0.1 V, frequency 100 Hz, and the scan rate was 200 mV/s. When the electrode was modified with metal-porphyrin or metal-phthalocyanines, the anodic peak currents of NO increased due to the catalytic oxidation of NO. In case of Fe(II)-phthalocyanine modified electrode, the peak currents remarkably increased and the sensitivity was high. The calibration curve had good linearity in the range from $3.6\;{\times}\;10^{-5}$ M to $7.2\;{\times}\;10^{-7}$ M, and the detection limit was $5.7\;{\times}\;10^{-7}$ M. For the structural stability and increased sensitivity, Fe(II)-phthalocyanine modified gold microdisk electrode coated with Nafion was applied to determination of NO released from cultured macrophase.

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