Some heavy metal concentration of surface sediments from the southwestern coast of Korea

서남해안 연근해저 퇴적물의 중금속 함량 및 분포

  • 전수경 (목포대학교 해양자원학과) ;
  • 조영길 (목포대학교 해양자원학과)
  • Published : 2002.12.01


Thirty sediment samples of the <63${\mu}{\textrm}{m}$ fraction collected from the southwestern coast of Korea were analysed for their heavy metal (Fe, Mn, Cr, Co, Cu, Ni, Zn and Pb) concentration. The results show that sediment texture plays a controlling role on the total metal concentrations and their spatial distribution. A single lM HCl extraction procedure was used in order to assess the environmental risk of heavy metals in bottom sediments. The non-residual fraction was the most abundant pool for Mn and Pb in most samples, which means that this metals are highly avaliable in these sediments. Cr, Ni, Fe, Co, Zn and Cu were mainly associated with the residual fraction, suggesting that their concentrations are controlled significantly by transport processes with the fine particles as carriers from diffuse pollution source. Concentration enrichment ratios(CER) were calculated from the non-residual contents and their values allowed us to classify the sediments according to their environmental risk.


  1. Hydrographic office, 1986, Technical reports, Pub. No. 1101.
  2. 김범수, 2001, 한반도 주변 연안 표층퇴적물의 중금속 오염평가, 서울대학교 박사학위논문, 178pp.
  3. Quevauriller, P.H., M. Laduca, E. Barahona, G. Rauret, A. Ure, A. Gomez, and H. Muntau, 1996, Interlaboratory comparison of EDTA and DTPA procedures prior to certification of extracble trace elements in calcareous soil, Sci. Total. Env., 178, 127-132.
  4. Folk, R.L., 1968, Petrology of Sedimentary Rock, Hemphills, 653pp.
  5. McBride, E.F., 1971, Mathematical treatment of size distribution data, In: Procedures in Sedimentary Petrology edited by RE. Carver, Wiley- Interscience, 109-127pp.
  6. Folk, R.L. and W.C. Ward, 1957, Brazos river bar: A study in the significance of grain size parameters, J. Sed. Petrol., 27, 3-26.
  7. 최만식, 정창식, 박계헌, 1994, 암석 용해방법에 따른 미량원소 분석결과 비교, 암석학회지, 3, 41-48.
  8. Szfer, P., G.P. Glasby, J. Pempkowiak, and R. Kaliszan, 1995, Extraction studies of heavy metal pollutants in surficial sediments from the southern Baltic Sea off Poland, Chem. Geol., 120, 111-126.
  9. Lee, S.H. and K.W. Lee, 1983, Heavy metals in sediments from Iinhae bay, Korea, J. Oceanological Soc. Korea, 18, 49-54.
  10. Jung, H.S., C.B. Lee, Y.G. Cho, and J.K. Kang, 1996, A mechanism for the enrichment of Cu and depletion of Mn in anoxic marine sediment, Banweol intertidal flat, Mar. Pollution Bull., 32, 782-787.
  11. Salomons, W. and U. Forstner, 1984, Metals in the Hydrocycle, Springer-Verlag, 349pp.
  12. Horowitz, A. J., 1991, A Primer on Sediment-Trace Element Chemistry, Lewis Publishers, INC., 136pp.
  13. Chester, R., 2000, Marine Geochemistry, Blackwell Science, 506pp.
  14. Forstner, U. and G.T.W. Wittmann, 1983, Metal pollution in the Aquatic Environment, Springer-Verlag, Belin. 486pp.
  15. Wedepohl, K.H., 1969, Handbook of Geochemistry, Springer-Verlag, Berlin.
  16. Muller, G., 1979, Schwermetalle in den Sedimenten des Rheins, Veranderungen seit 1971, Umschau, 79, 778-783.
  17. Martin, J.M. and M. Whitfield, 1983, The significance of river input of chemical elements to the ocean, In: Trace Metals in Sea Water edited by C.S. Wang, E. Boyle, J.D. Burton and ED. Goldberg, Plenum, New York, 265-298pp.
  18. Subramanian, V. and G. Mohanachandran, 1990, Heavy metals distribution and enrichment in the sediments of Southern East Coast of India, Mar. Pollut. Bull., 2, 324-330.
  19. Sahu, K.C. and U. Bhosale, 1991, Heavy metal pollution around the island city of Bombay, India. Part I: quantification of heavy metal pollution of aquatic sediments and recognition of environmental discriminants, Chem. Geol., 91, 263-283.
  20. Rubio, B., M.A. Nombela, and F. Vilas, 2000, Geochemistry of major and trace elements in sediments of the Ria de Vigo (NW Spain): an assessment of metal pollution, Mar. Pollut. Bull., 40, 968-980.
  21. Chester, R. and F.G. Voutsinou, 1981, The initial assessment of trace metal pollution in coastal sediment, Mar. Pollut. Bull., 12, 84-91.
  22. Hong, G.H., Y.A. Park, and K.W. Lee, 1983, Partitioning of heavy metals in sediments from Jinhae bay, Korea, J. Oceanological Soc. Korea, 18, 180-184.
  23. 조영길, 이창복, 최만식, 1994, 남해 대륙붕 표층 퇴적물 중 중금속 원소의 분포특성, 한국해양학회지, 29, 338-356.
  24. Ng, A. and C.C. Patterson, 1982, Changes of lead and barium with time in California offshore basin sediments, Geochim. Costrnochim, Acta, 46, 2307-2321.
  25. Hamelin, B., F. Grousset, and E.R. Sholkovitz, 1990, Pb isotopes in surficial pelagic sediments from the North Altantic, Geochim. Cosmochim. Acta, 54, 37-47.
  26. Monna, F., J. Dominik, J. L. Loizeau, M. Pardos, and P. Arpagaus, 1999, Origin and evolution of Pb in sediments of lake Geneva (Switzerland-France), Establishing a stable Pb record, Environ. Sci. Technol., 33, 2850-2857.
  27. Sutherland, R.A., 2000, Bed sediment-associated trace metals in an urban stream, Oahu, Hawaii, Environ. Geol., 39, 611-627.
  28. Sutherland, R.A., 2002, Comparison between non-residual Al, Co, Cu, Fe, Mn, Ni, Pb and Zn released by a three-step sequential extraction procedure and a dilute hydrochloric acid leach for soil and road deposited sediment, Applied Geochem., 17, 353-365.

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