Determination of DBCP and n-Butylbenzene using SPME with GC-MS

SPME-GC-MS를 이용한 DBCP 및 n-Butylbenzene의 분석

  • Park, Hyun-Mee (Advanced Analysis Center, Korea Institute of Science and Technology) ;
  • Kim, Young-Man (Advanced Analysis Center, Korea Institute of Science and Technology) ;
  • Lee, Dai-Woon (Department of Chemistry, Yonsei University) ;
  • Lee, Kang-Bong (Advanced Analysis Center, Korea Institute of Science and Technology)
  • 박현미 (한국과학기술연구원. 특성분석센터) ;
  • 김영만 (한국과학기술연구원. 특성분석센터) ;
  • 이대운 (연세대학교. 화학과) ;
  • 이강봉 (한국과학기술연구원. 특성분석센터)
  • Received : 2001.10.07
  • Published : 2001.12.25

Abstract

Solid phase microextraction(SPME) with $85{\mu}m$-polyacrylate (PA) and $100{\mu}m$-polydimethylsiloxane(PDMS) fibers, coupled to gas chromatography-mass spectrometry was used to determine 1,2-dibromo-3-chloropropane(DBCP) and n-butylbenzene in water. The conditions affecting the SPME process(i.e, extraction time, injection length, injection temperature, desorption time and temperature) were optimized. The linearity of the calibration curve (correlation coefficient, R) was over 0.99 and the limits of detection of the method were between 1.5 and $10.8{\mu}g/L$. Repeatability of the method was between 10.4 and 14.4 %.

Keywords

solid phase microextraction(SPME);GC/MS;DBCP;n-butylbenzene

References

  1. J. Colloid Interface Sci. v.47 C.H. Giles;A.P. D'Silva;I.A. Easton
  2. J.. Chromatogr. A v.839 A. Penalver;E. Pocurull;R.M. Marce
  3. J. Environ. Sci. Technol. v.26 C.K. Arthur;L.M. Kilam;Pawliszyn
  4. Solid Phase Microextraction: Theory and Practice J. Pawliszyn
  5. J.Chromatogr. A v.841 M.T. Kelly;M. Larroque
  6. J. Chromatogr. A v.795 C. Aguilar;S. Penalver;E. Pocerull
  7. J. Chromatogr. A v.872 E. Penalver;E. Pocurrull;R.M. Marce
  8. Trends in Anal. Chem. v.18 A. Penalver;E. Pocurull;F. Borrull;R.M. Marce
  9. Tox. Environ. Chem. v.55 A.M. Hanssan;E. Benfenati;R. Fanelli
  10. J. Chromatogr. A v.893 H. Tom;H.V.Langenhove
  11. Talanta v.51 A.S. Allonier;A. Bermond
  12. AppliedSpectroscopy v.54 M.J. Jager;D.P. McClintic;D.C. Tilotta
  13. Mar. Pollut. Bull v.32 G.A. Glegg;S.J. Rowland
  14. Toxicol. Appl. Pharmacol. v.59 W.M. Kluwe
  15. Human and Ecological Risk Assessment v.5 R.W. Risebrough
  16. Environ. Health Perspect v.103 S. Jobling;T. Reynolds;J.P. Sumpter
  17. Trends in Anal. Chem. v.18 H. Prosen;L.Z. Kralj
  18. Reproductive Toxicology v.9 B. Christine;R. Wiger;G. Brunborg
  19. Anal. Chem. v.70 Y. Yang;S.B. Hqwthorne;D.J. Miller
  20. J. Environ. Sci. Technol. v.28 D.W. Potter;J. Pawliszyn