Study on the Analytical Performance of Double Membrane Desolvator(DMD) with Perfluoroalkoxy(PFA) and Microconcentric Nebulizer(MCN) in Inductively Coupled Plasma Atomic Emission Spectrometry

유도결합 플라스마 원자방출 분광법에서 perfluoroalkoxy(PFA) nebulizer와 microconcentric nebulizer(MCN)을 이용한 double membrane desolvator(DMD)의 분석능력연구

  • Sul, Choon-Kuen (Division of Natural Science Dankook University) ;
  • Lim, H.B. (Division of Natural Science Dankook University)
  • 설춘근 (단국대학교 자연과학부) ;
  • 임흥빈 (단국대학교 자연과학부)
  • Received : 2000.12.06
  • Published : 2001.02.25

Abstract

In this work, analytical performance of a laboratory built double membrane desolvator (DMD) was studies using perfluoroalkoxy (PFA) nebulizer and microconcentirc nebulizer (MCN) in inductively coupled plasma atomic emission spectrometry. Compared with MCN, PFA nebulizer coupled to DMD showed similar analytical sensitivity for aqueous solution and better sensitivity for isopropyl alcohol. Since PFA resisted various acids, HCI, $H_2SO_4$ and HF solution were analyzed with less than 2% RSD. Rinse-out time for the signal reduction to 1% was obtained to be 35 s for PFA but about 45 s for MCN.

Keywords

ICP-AES;membrane desolvator;PFA nebulizer;MCN

Acknowledgement

Supported by : 한국과학재단(KOSEF)

References

  1. Amer.,Chem.Soc. v.56 no.7 Richard F.Browner;Andrew W.Boorn
  2. J,Anal.At.Spectrom v.11 D,G,Weir;M.W,Blades
  3. J.Anal.At.Spectrom v.9 D.G.Weir;M.W.Blades
  4. J.Anal,At.Spectrom v.9 D.G.Weir;M.W.Blades
  5. J.Anal.Arom.Spectrom. v.9 R.I.Botto;J.Zhu.
  6. Bull.Korean Chem.Soc. v.20 no.9 J.S.Lee;H.B.Lim
  7. J.Anal.Atom.Spectrom v.12 I.B.Brenner;A.Zander;M.Plantz;J.Zhu
  8. Fresnius J.Anal Chem. v.355 I.B.Brenner;J.Shu;A.Sander
  9. Spectrochim.Acta v.44B no.10 Kenneth Backstrom;A.Gustavsson;P.Hietala
  10. Spectrochim.Acta v.45B no.10 A,Gustavsson;P.Hietala
  11. Analytical Science & Technology v.11 no.4 Y,W,Heo;J,I.Gil;h.B.Lim
  12. Bull.Korean Chem.Soc. v.20 no.2 Y,S,Heo;H,B,Lim
  13. Micro v.63 Tracy Jacksier;Thoma J.;Gluodenis;Jr.;Robert J.Thomas
  14. Spectrochim.Acta v.43B no.8 A.Gustavsson
  15. Micro v.31 Jian-Go Chen;ManLi Wu
  16. Spectrochim.Acta v.45B no.9 A.Gustavsson;J.W.Lam
  17. Microchemical Journal v.64 no.1 Yongik Subg;H.F.Lim
  18. J,Anal,At.Spectrom v.11 D.G.Weir;M.W.Blades
  19. Micro v.39 Robert A.Aleksejczyk;Donld Gibilisco
  20. Micro v.51 Jian-Go Chen;ManLi Wu
  21. J.Anal.Atom.Spectrom v.11 R.I.Botto;J.Zhu.
  22. J.Anal.At.Spectrom. v.11 Robert I,Botto;Zim J,Jhu