The Electrochemical Characterization of$LiMn_{2-y}M_yO_4$ Cathode Material - II. Charge and Discharge Property and Cyclic Voltametry of $LiMn_{2-y}M_yO_4$ (M=Zn, Mg)

$LiMn_{2-y}M_yO_4$ 정극 활물질의 전기화학적 특성 - II. $LiMn_{2-y}M_yO_4$ (M=Zn, Mg)의 충방전 및 순환전위전류 특성

  • 정인성 (전남대학교 전기공학과) ;
  • 김종욱 (전북대학교 전자정보 사업단) ;
  • 구할본 (전남대학교 전기공학과) ;
  • 김형곤 (조선이공대학 전기과) ;
  • 손명모 (대구공업대학 세라믹공업과) ;
  • 박복기 (호원대학교 전기공학과)
  • Published : 2001.04.01

Abstract

Cathode materials $LiMn_{2-y}$$M_{y}$ $O_4$(M=Zn and Mg) were obtained by reacting the mixture of LiOH.$H_2O$, Mn $O_2$ and MgO ar ZnO at 80$0^{\circ}C$ for 36h in an air atmosphere. These materials showed an extended cycle life in lithium-anode cells working at room temperatue in a 3.0 to 4.3V potential window. Among these materials, LiM $n_{1.9}$M $g_{0.1}$ $O_4$ showed the best cycle performance in terms of the capacity and cycle life. The discharge capacities of the cathode for the Li/LiM $n_{1.9}$ $M_{0.1}$ $O_4$ cell at the 1st cycle and at the 70th cycle were about 120 and 105mAh/g, respectively. This cell capacity is retained by 88% after 70th cycle. In cyclic voltammetry measurement, all cells revealed tow oxidation peaks and reduction peaks. However, Li/$LiMn_{2-y}$$M_{y}$ $O_4$ cell substituted with Zn and Mg showed new reaction peak during reduction reaction.eaction.ion.ion.

References

  1. J. Power sources v.90 Capacity Fading of LiMn₂O₄electrode Synthesized by the emulsion drying methode S. T. Myung;H. T. Chung;S. Komaba;N. Kumagai;H.B. Gu
  2. Electrchimica Acta v.45 Electrochemical Properties of Carbon Composite Electrode with Polymer Electrlyte for Electric Double-Layer Capacitor H. B. Gu;J. U. Kim;H. W. Song;G. C. Park;B. K. Park
  3. 전기전자재료학회논문지 v.13 no.4 리튬 폴리머전지용 PVDF/PAN계 고분자 전해질의 이온 전도 특성 이재안;김종욱;구할본
  4. J. Phys. Chem. Solids v.57 no.12 Valence Analysis of Transition Metal Ions in Spinel $LiMn_{2-y}M_yO_4$ (M=Ti, Cr, Mn, Co) by Electron Energy Loss Spectroscopy S. Suzuki;M. Tomita;S. Okada;H. Arai
  5. 전기전자재료학회논문지 v.12 no.3 용매로써 물을 사용한 Sol-Gel법에 의해 제조된 LiMn₂O₄정극 활물질의 전기화학적 특성 정인성;구할본
  6. 전기전자재료학회논문지 v.12 no.4 열처리조건에 따른 LiMn₂O₄정극 활물질의 결정 구조와 전기화학적 특성의 변화 정인성;송희웅;이진;박계춘;박복기;구할본
  7. J. Electrochem. Soc. v.137 no.3 Electrocheistry of Manganese Dioxide in Lithium Nonaqueous Cell T. Ohzuku;M. KItagawa;T. Hirai