Mutual Separation of Am(III) and Eu(III) by Solvent Extraction with Cyanex 301

Cyanex 301에 의한 Am(III)과 Eu(III)의 상호분리

  • Received : 1998.09.03
  • Accepted : 1998.11.02
  • Published : 1999.02.10

Abstract

The present paper describes the solvent extraction behaviors and the mutual separation of Am and Eu by sulphur bearing Cyanex 301 acidic extractant in sodium nitrate solutions. Original Cyanex 301 was not able to separate the Am and Eu because of their similar extraction behaviors. The saponification of commercial Cyanex 301 was performed by small amounts of 8 M NaOH solutions and saponified Cyanex 301 was able to separate of Am from Eu with high selectivity in sodium nitrate aqueous solution. The separation factors ($SF_{Am/Eu}$) were increased with saponified ratio of commercial Cyanex 301, pH of sodium nitrate solution and initial concentration of Eu. To obtain the homogeneous saponified Cyanex 301, heterogeneous saponified Cyanex 301 was treated with addition of octyl alcohol or filtration. The observed $SF_{Am/Eu}$ was 32.3 for the former and 930 for the latter. Finally, the stripping behaviors of Am and Eu were similar and stripping yields showed 96.1% for the 1 M $NaNO_3$(pH=1.3) and 99% for the mixture solution of 0.05 M DTPA and 1.5 M lactic acid.

References

  1. final draft, NEA/PTS/DOC no.98 Status and assessment report on actinide and fission product partitioning and transmutation Partitioning and transmutation expert group of NEA(ed.)
  2. Principle and pratices of solvent extraction J. Rydberg(ed.);C. Musikas(ed.);G. R. Choppin(ed.)
  3. J. Korean Ind. & Eng. Chem. v.7 H. B. Yang;E. H. Lee;J. K. Lim;J. H. Yoo;H. S. Park
  4. 4th OECD/NEA International exchange meeting on partitioning and transmutation technology Partitioning of minor actinides from rare earths by solvent extraction with DEHPA H. B. Yang;J. K. Lim;J. H. Yoo
  5. J. Korean Ind. & Eng. Chem. v.8 H. B. Yang;E. H. Lee;J. K. Lim;J. K. Kim;J. S. Kim;J. H. Yoo
  6. Solvent. Extr. & Ion Exch. v.14 Y. Zhu;J. Chen;R. Jiao
  7. Global 97, Intern. Conf. on Future Nuclear Systems Y. Zhu;J. Chen;R. Jiao
  8. J. Radioanal. Nucl. Chem. v.228 G. Modolo;R. Odoj
  9. Global 97, Intern. Conf. on Future Nuclear Systems C. Hill;C. Madic;P. Baron;M. Ozawa;Y. Tanaka