Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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A Study on the Preparation of Nylon6,6/Polypyrrole Conducting Composite

Nylon6,6/Polypyrrole 전도성 복합체의 제조에 관한 연구

  • Lee, Wan-Jin (Faculty of Applied Chemistry, College of Engineering, Chonnam National University) ;
  • Kim, Hyo-Yong (Faculty of Applied Chemistry, College of Engineering, Chonnam National University)
  • 이완진 (전남대학교 공과대학 응용화학공학부) ;
  • 김효용 (전남대학교 공과대학 응용화학공학부)
  • Received : 1998.09.30
  • Accepted : 1998.12.22
  • Published : 1999.04.10

Abstract

The conducting composites were prepared by blending polypyrrole (PPy) as a conducting polymer and nylon6,6 as a matrix. In chemical polymerization of PPy, the oxidizing agent was $FeCl_3$ and dopant was alkylbenzenesulfonic acid, such as camphorsulfonic acid (CSA) or dodecylbenzene sulfonic acid (DBSA). The electrical conductivity and mechanical properties were measured for the amount of dopant and PPy complex, and these morphology observed. When it was doped with DBSA having long alkyl chain and added the PPy complex of 25 wt %, the electrical conductivity was increased up to 0.64 S/cm.

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Acknowledgement

Supported by : 한구과학재단

References

  1. J. Chem. Soc. Chem. Comm. H. Shirakawa;E. J. Louis;a. G. McDiarmid;C. K. Chiang;A. J. Heeger
  2. J. Chem. Soc. Chem. Comm. A. F. Diaz;K. Kanazawa;G. D. Gadini
  3. J. Chem. Soc. Chem. Comm. J. F. Rabolt;T. C. Clarke;K. K. Kanazawa
  4. Polymer. Comm. v.23 M. E. Galvin;G. E. Wnek
  5. Appl. Phys. Lett. v.60 Y. Cao;G. M. Treacy;P. Smith;A. J. Heeger
  6. Synth. Met. v.52 Y. Cao;A. J. Heeger
  7. Phys. Rev. B v.48 K. Lee;A. J. Heeger;Y. Cao
  8. Synth. Met. v.65 A. G. MacDiarmid;A. J. Epstein
  9. Synth. Met. v.72 J. K. Avlyanov;Y. Min;A. G. MacDiarmid;A. J. Epstein
  10. Materials Science and Engineering, (3rd ed.) W. D. Callister
  11. Synth. Met. v.69 A. G. MacDiarmid;A. J. Epstein
  12. J. Chem. Soc. Chem. Comm. H. W. Gibson;F. C. Bailey;A. J. Epstein;H. Romelmann;J. M. Bochan
  13. Synth Met. v.1 L. W. Shachlette;R. R. Chance;D. M. Ivory;G. G. Miller;R. H. Baughman
  14. Synth. Met. v.74 J. Y. Lee;D. Y. Kim;C. Y. Kim
  15. Materials Research Society v.11 A. Lekatou;S. E. Faidi;S. B. Lyon;R. C. Newman
  16. Synth. Met. v.48 Y. Cao;P. Smith;A. J. Heeger