Synthesis of Various Siloxylcellulose Derivatives

Siloxylcellulose 유도체의 합성

  • 홍재진 (단국대학교 이과대학 화학과) ;
  • 양재건 (단국대학교 이과대학 화학과)
  • Received : 1998.09.28
  • Accepted : 1998.12.08
  • Published : 1999.04.10


Cellulose has three hydroxyl groups with different reactivity. By substitution reaction, trimethylsiloxyl-, vinyldimethylsiloxyl-, allyldimethylsiloxyl-, phenyldimethylsiloxyl-, 3,3,3-trifluoropropyldimethylsiloxyl- and tris(trimethylsiloxy)siloxylcellulose were synthesized IR, NMR, and elemental analysis were used for confirming their structures, degree of substitution (D.S.) and the reactivity of siloxylation agent, respectively. The D.S. values were 2.5, 2.2, 2.1, 2.2, 2.6, 0.7 for the corresponding siloxylcellulose.


Supported by : 단국대학교


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