Synthesis of Copolyimide Containing 5,15-Bis(mesityl)-10,20-bis(4-amino)porphyrin

5,15-Bis(mesityl)-10,20-bis(4-amino)porphyrin을 포함하는 Copolyimide의 합성

  • Kim, Hooi-Sung (Department of Polymer Science and Engineering, Pusan National University) ;
  • Lee, Min-Ho (Department of Polymer Science and Engineering, Pusan National University) ;
  • Kim, Chun-Ho (Department of Polymer Science and Engineering, Pusan National University) ;
  • Kim, Mi-Ra (Department of Polymer Science and Engineering, Pusan National University) ;
  • Lee, Jin-Kook (Department of Polymer Science and Engineering, Pusan National University)
  • 김휘성 (부산대학교 고분자공학과) ;
  • 이민호 (부산대학교 고분자공학과) ;
  • 김춘호 (부산대학교 고분자공학과) ;
  • 김미라 (부산대학교 고분자공학과) ;
  • 이진국 (부산대학교 고분자공학과)
  • Received : 1998.06.16
  • Accepted : 1999.08.12
  • Published : 1999.10.10

Abstract

5,15-Bis(mesityl)-10,20-bis(4-amino)porphyrin was synthesized with meso-(mesityl)dipyrromethane and 4-nitrobenzaldehyde. It was characterized with $^1H$-NMR spectroscopy, UV spectrophotometer, and GC-MASS. In UV spectrum, Soret-band(438 nm) and Q-bands(526, 572, 611 nm) were confirmed. In NMR spectrum, the characteristic peak of porphyrin was detected at -2.65 ppm. Copolyimide containing porphyrin structure was synthesized with mesityl-$TPP(NH_2)$, 3,3',4,4'-benzophenonetetracarboxylic dianhydride(BTDA) and 2,2-bis(4-(4-aminophenoxy)phenyl) hexafluoropropane(BAPHF) and characterized with UV and FT-IR spectrophotometer. The $T_g$ and $T_m$ of the synthesized copolyimide were 220.7 and $369.2^{\circ}C$, respectively.

Keywords

porphyrin;copolymide;Soret band;Q-band;imidization

Acknowledgement

Supported by : 부산대학교

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