The Effect of Plasma on Hydrophilic Surface Modification of LDPE

저밀도 폴리에틸렌의 친수성 표면개질에 미치는 플라즈마의 영향

  • 황승노 (단국대학교 화학공학과) ;
  • 전법주 (단국대학교 화학공학과) ;
  • 정일현 (단국대학교 화학공학과)
  • Received : 1998.01.09
  • Accepted : 1998.03.05
  • Published : 1998.06.10

Abstract

The effect of hydrophilic surface modification of low density polyethylene(LDPE) byt the plasma gas($O_2$, $N_2$, and $O_2/N_2$) was investigated from the point of view of the functionalities of the generated LDPE surfaces and the contact angle. By virtue of x-ray photoelectron spectra(XPS) and attenuated total reflectance(FT-IR ATR) analysis, the LDPE surfaces treated with plasma were generated with oxygen functionalities of carbonyl, carboxyl, and the like, nitrogen functionalities by nitrogen plasma and mixing of nitrogen and oxygen plasma treatment were identified with. It was found that nitrogen plasma treatment showed with minimum value at contact angle for rf-power and treatment time, we had obtained optimum condition for hydrophilic surface modification at composite parameter, [(W/FM)t] 520~550GJs/kg.

Keywords

Acknowledgement

Supported by : 단국대학교

References

  1. Polymer v.38 A. Nihlstrand;T. Hjertberg;K. Johansson
  2. J. Appl. Polym. Sci. v.64 N. Inagaki;S. Tasaka;H. Kawai;Y. Yamada
  3. Plasma Polymerization H. Yasuda
  4. J. Appl. Polym. Sci v.63 J. R. Chen;T. Wakida
  5. J. Appl. Polym. Sci : Appl. Polym. Symp. v.46 N. Inagaki;S. Tasaka;J. Ohkubo;H. Kawai
  6. J. Appl. Polym. Symp. v.42 E. Occhiello;M. Morra;G. Morini;F. Garbassi;P. Humphrey
  7. J. Appl. Polym. Sci : Appl. Polym. Symp v.42 Y. Iriyama;H. Yasuda
  8. Polymer v.38 A. Nihlstrand;T. Hjertberg;K. Johansson
  9. Polymer v.38 A. Nihlstrand;T. Hjertberg;K. Johansson
  10. Macromolecules v.29 E. T. Kang;K. L. Tan;K. Kato;Y. Uyama;Y. Ikada
  11. J. Appl. Polym. Sci. : Appl. Polym. Symp. v.42 R. E. Marchant;C. J. Chou;C. Khoo
  12. J. Appl. Polym. Sci. Polym. Chem. Ed v.33 N. Inagaki;S. Tasaka;H. Kawai