A Study on the Synthesis of Cationic Fiber-Softener HEC-2-HP-AC Ether Derivatives

양이온성 섬유유연제 HEC-2-HP-AC Ether 유도체의 합성에 관한 연구

  • Kang, Ik Joong (Department of Chemical Engineering, Kyungwon University)
  • 강익중 (경원대학교 공과대학 화학공학과)
  • Received : 1998.04.10
  • Accepted : 1998.05.20
  • Published : 1998.08.10


Cellulose was reacted with ethylene oxide to get hydroxyethylcellulose. Quaternary ammonium salt was produced by reaction of epichlorohydrin and trialkylamine. The epoxide ring was opened by acid addition to 3-chloro-2-hydroxypropyltrialkylammonium chloride. Previously unreported two compounds, hydroxyethylcellulose-2-hydroxypropylammonium chloride ether and hydroxyethylcellulose-2-hydroxypropyltriethylammonium chloride ether were synthesized by substitution reaction of hydroxyethylcellulose with glycidyltrialkylammonium chloride or 3-chloro-2-hydroxypropyl-glycidyltrialkylammonium trialkylammonium chloride. All of the compounds including starting materials and reaction intermediates were characterized by $^1H$-NMR and FT-IR spectroscopy.


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