Syntheses of New Lactones Containing Phenyl or Methyl Groups

페닐기 및 메틸기를 포함하는 새로운 lactone의 합성

  • 장승현 (대구대학교 자연과학대학 화학과) ;
  • 문상칠 (대구대학교 자연과학대학 화학과) ;
  • 김학희 (선문대학교 공과대학 화학공학부) ;
  • 이갑득 (동국대학교 자연과학대학 화학과) ;
  • 정광보 (한서대학교 공과대학 화학공학과)
  • Received : 1998.04.21
  • Accepted : 1998.07.24
  • Published : 1998.11.10

Abstract

Four new lactones and one dibenzo crown ether were synthesized by reaction of dihydroxy compound with oxalyl chloride and with ${\alpha}$,${\omega}$-dibromo compound, respectively. 5,6,11,12-Tetracarbonyl-2,2,3,3,8,8,9,9-octaphenyl-1,4,7,10-tetraoxacyclodode- cane(1), 5,6,11,12-tetracarbonyl-2,2,3,3,8,8,9,9-octamethyl-1,4,7,10-tetraoxacyclododecane(2), 7,8,15,16-tetracarbonyl-1,6,9,14-tetraoxacylclohexadecane(3), and 5,6,11,12-tetracarbonyl- 2,3,8,9- tetraphenyl-1,4,7,10-tetraoxacyclododecane(4) were prepared by reaction of oxalyl chloride with benzopinacol, pinacol, 2,2'-dihydroxybiphenyl and hydrobenzoin, respectively, in the presence of pyridine. Dibenzo-13-crown-4 (5) was obtained by reaction of catechol with 1,3-dibromopropane/1,2-dibromoethane.

Acknowledgement

Supported by : 대구대학교

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