Bromination of Alkyl Chlorides by LiBr and CaBr2 adsorbed on Alumina

LiBr와 CaBr2가 흡착된 알루미나상에서 일어나는 염화 알킬의 브롬화반응

  • Received : 1996.04.17
  • Accepted : 1996.07.16
  • Published : 1996.10.10

Abstract

Several alkyl chlorides were brominated using LiBr and $CaBr_2$ adsorbed on alumina in the absence of solvent. The yields of alkyl bromides were fairly high. Such a high reactivity by these bromide salts might be due to the interaction of minute amount of water and the salt on alumina. Differential scanning calorimetry (DSC) thermogram was provided and discussed.

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