Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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A Study over Catalytic Behavior Octane Enhancer, TAME Synthesis with Ion Exchange Resin Catalysts

이온교환수지 촉매를 이용한 옥탄가 향상제인 TAME 합성반응의 연구

  • Park, Jin-Hwa (Dept. of Chem. Eng., College of Eng., Chonnam Nat'l Univ.)
  • 박진화 (전남대학교 공과대학 화학공학과)
  • Received : 1995.11.07
  • Accepted : 1996.08.28
  • Published : 1996.10.10

Abstract

TAME synthesis was studied in a fixed bed reactor with 3 different types of exchanged resins i.e, Amberlyst-15, Amberlyst-15(wet) and Amberlyst XN-1010. Amberlyst-15 has highest activity, presumably due to the higher reaction participation of the inner active sites of gel shape microparticular resin structure. The optimum reaction conditions for TAME synthesis were found as follows ; reaction temperature of $135^{\circ}C$, molar ratio(MeOH/I.A.A) of 1.0~4.0 and W/F of 2.0~4.0 gr.-cat. hr/gr.-mole. The cross-linking bond of styrene divinyl benzene was observed at $2{\theta}=20$ in XRD pattern. The DSC analysis showed that the thermal stability was in order of Amberlyst-15>Amberlyst-15(wet)>Amberlyst XN-1010. The apparent activation energies of TAME synthesis reaction with Amberlyst-15, Amberlyst-15(wet) and Amberlyst XN-1010 were 12.36, 12.46 and 14.72 kcal/mole, respectively.

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