Synthesis of Poly(alkylene carbonate) from Carbon Dioxide

이산화탄소로부터 Poly(alkylene carbonate)의 합성

  • Lee, Yoon-Bae (Dept. of Chem. Eng., College of Eng., Soonchunhyang Univ.) ;
  • Choi, Jeong-Hyun (Dept. of Chem. Eng., College of Eng., Soonchunhyang Univ.)
  • 이윤배 (순천향대학교 공과대학 화학공학부) ;
  • 최정현 (순천향대학교 공과대학 화학공학부)
  • Received : 1996.07.16
  • Accepted : 1996.08.27
  • Published : 1996.10.10

Abstract

In order to reduce carbon dioxide, one of the major greenhouse gases, a new type of copolymer, poly(alkylene carbonate) has been synthesized. The alternating copolymers have been obtained from carbon dioxide and various epoxides with zinc carboxylate as a catalyst. The number-average molecular weight of the polymer is about 50,000 and polydispersity is rather broad(5~10). The polymers are amorphous, and glass-clear materials that exhibit unusually facile and clean thermal decomposition behavior. Complete decomposition with no carbon residue is observed at elevated temperature even in an inert atmosphere. Terpolymers with bulkier epoxides improve the physical properties of the copolymer with simple epoxides. The decomposition properties of the polymer provide versatile applications such as ceramic, metal, and electronic binders and lost-foam casting. Further application of the polymer for the barrier film or the plasticizer will be investigated.

Keywords

Acknowledgement

Supported by : 한국과학재단

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