Conversion of Methanol to Hydrocarbons over Heteropoly Acids(II)

헤테로폴리산 촉매에 의한 탄화수소로의 메탄올 전환반응(II)

  • Hong, Seong-Soo (Dept. of Chemical Engineering, Pusan National University of Technology) ;
  • Lim, Ki-Chul (Science and Technology Policy Institute) ;
  • Lee, Ho-In (Dept. of Chemical Technology, College of Engineering, Seoul National University)
  • 홍성수 (부산공업대학 화학공학과) ;
  • 임기철 (과학기술정책연구소) ;
  • 이호인 (서울대학교 공업화학과)
  • Received : 1993.01.18
  • Accepted : 1993.04.12
  • Published : 1993.05.01


In the conversion of methanol, the effect of acide property of heteropoly compounds on the catalytic activity was investigated. The pretreatment of Cu-exchanged 12-tungstophosphoric acid with hydrogen enhanced both the selectivity for propane and the conversion of methanol, and the pretreatment of Al-exchanged 12-tungstophosphoric acid with water enhanced the acid strength of the catalyst. The water added into the reactant decreased the conversion of methanol, while the pretreatment temperature did not affect it but the propylene/propane ratio. Various partially-substituted Al salts of 12-tungstophosphoric acid showed different catalytic activities depending on the degree of Al-substitution.



Supported by : 한국학술진흥재단