Separation of Non-Volatile Compounds Unsuitable for GC Using Supercritical Fluid as Mobile Phase

초임계 유체를 이동상으로 사용함으로써 기체 크로마토그래피로 분리하기 힘든 비휘발성 화합물들의 분리

  • Pyo, Tong Jin (Department of Chemistry, Kang Weon National University) ;
  • Kim, Hoon Ju (Chemical Analysis Center, Lucky Central Research Institute)
  • 표동진 (강원대학교 자연과학대학 화학과) ;
  • 김훈주 (럭키중앙연구소 분석센터)
  • Received : 1992.03.16
  • Published : 1992.06.25


In this work, we developed supercritical fluid chromatographic methods for the samples which are difficult to analyze with conventional GC or HPLC. Long-chain Hydrocarbons, mink oils and soybean oils unsuitable for GC because of their low volatility or limited thermal stability were separated by SFC due to the high solvating properties of supercritical carbon dioxide fluids. In our research, a new method for the analysis of polar fatty acids and pesticides was developed. This method should be used to overcome problems with polar samples in SFC.