Temperature Dependence on the Binding of the Homologs of Methyl Orange by Crosslinked Poly(4-vinylpyridine). 6. Effect of Crosslinking Agent

가교폴리 (4-비닐피리딘) 과 메틸오렌지동족체와의 결합에 대한 온도의 존성. 6. 가교제의 영향

  • Lee, Suck-Kee (Department of Polymer Science, Kyungpook National University) ;
  • Park, Nam-Kyu (R & D Center, Kolon Industries, Inc.) ;
  • Kim, Woo-Sik (Department of Polymer Science, Kyungpook National University)
  • 이석기 (경북대학교 고분자공학과) ;
  • 박남규 ((주) 코오롱 기술연구소) ;
  • 김우식 (경북대학교 고분자공학과)
  • Received : 1990.11.29
  • Published : 1990.12.31


Various crosslinked poly(4-vinylpyridines) having different degrees of crosslinking were prepared by radical copolymerizations of 4-vinylpyridine with N, N'-2, 6-pyridinebisacrylamide as a crosslinker. The abilities of these crosslinked polymers to bind methyl orange and butyl orange were investigated at various temperatures in a buffer solution of pH 7. The first binding constants were evaluated from the equilibrium binding amounts. The first binding constants against the temperatures showed bell-shaped curves. Also, the first binding constants against the degree of crosslinking showed bell-shaped curves. When the temperature and the degree of crosslinking of maximum binding in the curves of these binding systems were compared with those of previous systems containing crosslinked poly(4-vinylpyridines) prepared by using N, N'-methylenebisacrylamide, N, N'-tetramethy-lenebisacryamide and divinylbenzene as crosslinkers, respectively, they were varied with the crosslinked poly(4-vinyl pyridines) containing different crosslinkers. These results were discussed in terms of the properties of the crosslinkers.