Synthesis of Polyphenylene-1,2,4-Owadiazoles and Quinone Polymer by the Reactions of Tere- and Iso-Phthalohydroxamoyl Chlorides with Bisdipolarophiles

  • Suck-Ju Hong (Department of Chemical Engineering, Kon-kuk University)
  • Published : 1971.06.30


Tere-and Isophthalohydroxamoyl chlorides were condensed with 1, 4-benzoquinone to afford quinone type polymer with the oxidation of the ring structure. Similarly, tere-and isophthalohydroxamoyl chlorides were condensed with tere-and isophthaldioximes and terephthalonitrile to give crystalline polyphenylene-1,2,4-oxadiazoles, among which the reaction product of terephthalohydroxamoyl chloride with terephthalonitrile in xylene afforded the highest crystallinity.



  1. Proceeding Chem. Soc. R. Huisgen
  2. Angew. Chem. v.75 R. Huisgen
  3. Bull. Chem. Soc. Japan v.41 Y. I wakura;S. Shiraishi
  4. Polymer Journal v.2 no.136 S.J. Hong;Y. Iwakura;K. Uno
  5. J. Synthetic Org. Chem. Japan v.28 T. Sasaki
  6. Bull. Chem. Soc. Japan v.41 T. Sasaki;T. Yoshioka
  7. Gazz. Chim. Ital. v.80 A. Quilico;C. Stano;D'Alcontres
  8. Polymer Letters v.3 C. G. Overberger;S. Fujimoto
  9. J. Polymer Sci. v.3 Y. Iwakura;K. Uno;S. Hara
  10. J. Org. Chem. v.28 M. S. Chang;A. J. Matuszko
  11. Bull. Chem. Soc. v.37 Y. Iwakura;M. Akiyama;K. Nagakubo