한국지하수토양환경학회:학술대회논문집 (Proceedings of the Korean Society of Soil and Groundwater Environment Conference)한국지하수토양환경학회 (Korean Society of Soil and Groundwater Environment)
Partitioning tracer tests were conducted to quantify the saturation degree of diesel and water in unsaturated soil, respectively. The use of partitioning tracers that partition into diesel, water, and air (i.e., three-phase partitioning), is in attractive alternative to traditional coring and analysis method. These gaseous partition tracers not global warming gas like CFC's are Butane, Acetylene, Ethylene, Methylene chloride, and Methane. The glass column packed with sandy soil was prepared, in which a three-phase system of air, water, and diesel was maintained. Conservative and partition gas tracers were injected into the columns and detected easily using a single GC detector(FID). For each tracer, a method of moments was used to estimate partition coefficient between water, diesel. and the air, respectively. The results from the column studies showed that the diesel/air tracer partition coefficient ranged from 8.2 to 868 and 9.2 for water/air. Saturation degree of diesel and water in the column, predicted by the partition coefficients obtained from tests, was underestimated up to 66% and 23% respectively.